Gibbs Free Energy Calculator

Enter your Calculation Method, then plug in Enthalpy Change (ΔH), Entropy Change (ΔS), and Temperature — or use an Equilibrium Constant (K) — and this Gibbs Free Energy Calculator gives you Gibbs Free Energy (ΔG), Standard Gibbs Energy (ΔG°), and tells you whether your reaction spontaneity is favorable or not.

kJ/mol

Positive for endothermic, negative for exothermic reactions

J/(mol·K)

Positive for increased disorder, negative for decreased disorder

K

Temperature in Kelvin (K = °C + 273.15)

Only for equilibrium constant method

Results

Gibbs Free Energy (ΔG)

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Reaction Spontaneity

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Standard Gibbs Energy (ΔG°)

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Energy Components

Frequently Asked Questions

How do I calculate Gibbs free energy?

Gibbs free energy is calculated using ΔG = ΔH - TΔS, where ΔH is enthalpy change, T is temperature in Kelvin, and ΔS is entropy change. Alternatively, you can use ΔG° = -RT ln K for equilibrium constant calculations.

What does it mean when Gibbs free energy is negative?

A negative ΔG indicates that the reaction is thermodynamically favorable and will occur spontaneously under the given conditions without external energy input.

Why is Gibbs free energy 0 at equilibrium?

At equilibrium, there is no net change in the system, meaning no driving force exists for the reaction to proceed in either direction. This state corresponds to ΔG = 0.

How to determine if a reaction is spontaneous or nonspontaneous?

If ΔG < 0, the reaction is spontaneous. If ΔG > 0, the reaction is nonspontaneous and requires external energy. If ΔG = 0, the system is at equilibrium.

What units should I use for enthalpy and entropy?

Enthalpy is typically expressed in kJ/mol, while entropy is in J/(mol·K). Make sure units are consistent - convert kJ to J or vice versa to match your entropy units.

What information does Gibbs free energy give about a reaction?

Gibbs free energy tells you whether a reaction will occur spontaneously, the maximum useful work that can be extracted from the reaction, and helps predict the direction of chemical processes.

Can temperature affect the spontaneity of a reaction?

Yes, temperature can change reaction spontaneity. Since ΔG = ΔH - TΔS, increasing temperature amplifies the entropy term, which can make endothermic reactions spontaneous at high temperatures.

What is the difference between ΔG and ΔG°?

ΔG° is the standard Gibbs free energy change under standard conditions (298.15 K, 1 atm pressure, 1 M concentrations), while ΔG applies to any specific conditions including non-standard states.

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